(4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate

被引：0
|
作者：
Kassim, Mohammad B. [1 ]
McCleverty, Jon A. [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536810048233
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Mo(C15H22BN6)Cl(NO)(C9H13N)]center dot CH2Cl2, the Mo I atom adopts a distorted MoClN5 octahedral geometry with the hydrotris(3,5-dimethylpyrazolyl)borate anion in an N,N',N ''-tridentate tripodal (facial) coordination mode. A 4-tert-butylpyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo I atom and an intramolecular C-H center dot center dot center dot Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an intermolecular C-H center dot center dot center dot Cl hydrogen bond involving the complex molecule and the CH2Cl2 solvent molecule.
引用
收藏
页码：M1696 / U1912
页数：14
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