Coordination chemistry of acrylamide 6:: Formation and structural characterization of [Fe(O-OC(NH2)CH=CH2)6][Fe2OCl6]

被引：11

作者：

Girma, Kibatu B. ^{[1
]}

Lorenz, Volker ^{[1
]}

Blaurock, Steffen ^{[1
]}

Edelmann, Frank T. ^{[1
]}

机构：

[1] Otto Von Guericke Univ, Inst Chem, D-39106 Magdeburg, Germany

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 01期

关键词：

acrylamide; iron(II) complex; iron(Ill) complex; coordination chemistry; crystal structure;

D O I：

10.1016/j.ica.2007.06.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new acrylamide iron(II)/iron(III) complex [Fe(O-OC(NH2)CH=CH2)(6)][Fe2OCl6] (1) was obtained by the reaction of a mixture of anhydrous FeCl2 and anhydrous FeCl3 with acrylamide (molar ratio 1:2:6) in 98% pure commercial nitromethane under nitrogen atmosphere. According to an X-ray structural analysis, the acrylamide ligands in the cation are coordinated via the amide-oxygen atoms. The formation of the (mu-oxo)bis[trichloroferrate(III)](2-) anion presumably resulted from partial hydrolysis of FeCl3 or [FeCl4](-) by small amounts of water in the nitromethane and/or by the nitromethane itself. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：346 / 348

页数：3

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