TRITERPENE GLYCOSIDES FROM Astragalus AND THEIR GENINS. XC. ASKENDOSIDE K FROM Astragalus taschkendicus

被引:6
|
作者
Isaev, I. M. [1 ]
Isaev, M. I. [1 ]
机构
[1] Uzbek Acad Sci, S Yu Yunusov Inst Chem Plant Subst, Tashkent 700135, Uzbekistan
关键词
Astragalus taschkendicus; Leguminosae; triterpene glycosides; askendoside K; cycloorbigenin C; PMR; C-13; NMR; DEPT; COSY; Hetcor; NOE spectra; CYCLOARTANES;
D O I
10.1007/s10600-011-0002-6
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
A new triterpene cycloartane glycoside called askendoside K was isolated from roots of Astragalus taschkendicus Bunge (Leguminosae). The structure of this glycoside was established using chemical and biochemical transformations and spectral data. Askendoside K was a bisdesmoside of cycloorbigenin C and had the structure 23R, 24R-cycloartan-3 beta,6 alpha,16 beta,23,24,25-hexaol 3-O-[(alpha-L-arabinopyranosyl)(1 -> 2)-beta-D-xylopyranoside], 23-O-[(beta-D-glucuronopyranosyl)(1 -> 2)-beta-D-glucopyranoside].
引用
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页码:587 / 591
页数:5
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