New NLO active cyclopalladated chromophores in main-chain polymers

被引：23
|
作者：
Cariati, F
Caruso, U
Centore, R
De Maria, A
Fusco, M
Panunzi, B
Roviello, A
Tuzi, A
机构：
[1] Univ Naples Federico II, Dipartimento Sci Alimenti, I-80055 Portici, Naples, Italy
[2] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Anali, I-20133 Milan, Italy
[3] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 02期
关键词：
cyclopalladated complexes; nonlinear optics; main-chain polymers;
D O I：
10.1016/S0020-1693(03)00495-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new OH-functionalized orthopalladated complexes bearing an electron-donor and an acceptor group in a trans-like arrangement with respect to the metal have been prepared and characterized. The ligands are Schiff bases, bound as C,N- or N, O-chelating moieties. Four new polyesters were obtained by polycondensation from the monomeric complexes and pentyloxyterephthaloyl chloride. Two "model" complexes, each one related to one monomer, were also synthetized, in order to obtain further and more detailed characterization data, and in particular to perform measurements of mubeta. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：548 / 556
页数：9
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