Pressure effect studies on spin crossover systems

被引：217

作者：

Gütlich, P ^{[1
]}

Ksenofontov, V ^{[1
]}

Gaspar, AB ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 17-18期

关键词：

spin crossover; pressure; phase transitions; hysteresis; elastic interactions;

D O I：

10.1016/j.ccr.2005.01.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the present review article we discuss the results of investigations of the influence of hydrostatic pressure (up to 1.2 GPa) on the spin transition behaviour in coordination compounds of 3d transition metal ions. The systems under investigation are mononuclear spin crossover compounds of iron(II) and chromium(II), dinuclear complexes of iron(II) exhibiting coexistence of intramolecular anti-ferromagnetic coupling and thermal spin crossover, and 1D, 2D and 3D polynuclear spin crossover complexes of iron(II). It is demonstrated that the application of hydrostatic pressure serves as a tool for modifying the ligand field strength in a controlled manner. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1811 / 1829

页数：19

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