Effects of organic matter on polycyclic aromatic hydrocarbons in riverine sediments affected by human activities

Organic matter (OM) is an important component of riverine environments and a major factor in the migration and transformation of hydrophobic organic substances, such as polycyclic aromatic hydrocarbons (PAHs), to sediments. We studied the distributions, sources, and correlations between PAHs and OM in sediments from the Duliujian and the Beiyun rivers in North China. Sixteen PAHs were detected in the surface sediments at total concentrations ranging from 356 to 4652 ng.g(-1) dry weight, which caused a moderate to high level of pollution. The PAH distributions were significantly and positively correlated with OM (p < 0.01) and higher concentrations were detected downstream of areas affected by human activity. Petroleum, coal, and wood combustion were the main sources of PAHs in riverine sediments, and the sources of OM in sediment included terrestrial and aquatic higher plants, soil, and sewage discharge. The OM accumulated and aged along the river, with increases in the degree of aromaticity and condensation, which led to stronger adsorption of PAHs. Our results will help to promote the management and restoration of contaminated riverine sediments.