Photoredox reaction of chloromercurioferrocene induced by metal-to-metal charge transfer excitation

被引：2

作者：

Kunkely, H ^{[1
]}

Vogler, A ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2001年 / 143卷 / 2-3期

关键词：

absorption spectra; charge transfer; ferrocene; mercury(II);

D O I：

10.1016/S1010-6030(01)00494-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electronic spectrum of (C5H5FeC5H4)-C-II-(HgCl)-Cl-II shows a Fe-II to Hg-II metal-to-metal charge transfer (MMCT) absorption at lambda (max) = 300 nm. The photolysis of the complex in ethanol/HClO4 mixtures induced by MMCT excitation leads to the formation of [(C5H5FeC5H5)-C-III](+) and elemental mercury with phi = 7 x 10(-3) at lambda (irr) = 313 nm. @ 2001 Elsevier Science B.V. All rights reserved.

引用

页码：209 / 211

页数：3

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