Synthesis and spectroscopic characterization of dimethyl/di(n-butyl)tin(IV)bis(O,O′-ditolyl dithiophosphate) complexes.: Crystal structures of Me2Sn[S2P(OC6H4Me-o)2]2 and n-Bu2Sn[S2P(OC6H4Me-o)2]2

被引：18

作者：

Drake, John E.

Gurnani, Chitra

Hursthouse, Michael B.

Light, Mark E.

Nirwan, Manisha

Ratnani, Raju ^{[1
]}

机构：

[1] MDS Univ, Dept Pure & Appl Chem, Ajmer 305009, India

[2] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2007年 / 21卷 / 07期

关键词：

organotin(IV) complexes; di(o-; m- or p-tolyl) dithiophosphates; X-ray crystal structures; NMR spectroscopy;

D O I：

10.1002/aoc.1265

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Organotin(IV) complexes of the type, R2Sn[S2P(OR')(2)](2) (where R = Me, n-Bu and R' = o-, m-, p-C6H4Me) have been obtained by the reaction of Me2SnCl2 or n-Bu2SnCl2 with ammonium salts of the corresponding O,O'-ditolyl dithiophosphates on stirring in benzene and have been characterized by elemental analysis and IR, H-1, C-13, P-31 and Sn-119 NMR spectroscopy. Trends in data are discussed. The crystal structures of Me2Sn[S2P(OC6H4Me-o)(2)](2) and n-Bu2Sn[S2P(OC6H4Me-o)(2)](2) are reported. The environment around the tin atom in both molecules may be described as having skew-trapezoid bipyramidal geometry. Copyright (c) 2007 John Wiley & Sons, Ltd.

引用

页码：539 / 544

页数：6

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