Mesoporous materials as supports of Rh catalysts. Synthesis, characterization and catalytic application

被引：0
|
作者：
Blanco, Carmen [1 ]
Krstic, Vesna [1 ]
Pesquera, Carmen [1 ]
Perdigon, Ana [1 ]
Gonzalez, Fernando [1 ]
机构：
[1] Univ Cantabria, Grp Inorgan Chem, E-39005 Santander, Spain
来源：
ZEOLITES AND RELATED MATERIALS: TRENDS, TARGETS AND CHALLENGES, PROCEEDINGS OF THE 4TH INTERNATIONAL FEZA CONFERENCE | 2008年 / 174卷
关键词：
Nanomaterials MCM-41; Rh/MCM-41; Catalysts; Rh-Sn/MCM-41; Crotonaldehyde Hydrogenation; ALPHA; BETA-UNSATURATED ALDEHYDES; SELECTIVE HYDROGENATION; CROTONALDEHYDE; RHODIUM; BONDS;
D O I：
暂无
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Mesoporous materials, MCM-41 and silica-supported Rh catalysts and Rh promoted with Sn catalysts, have been prepared by using organometallic complex as metal precursor and tin (II) acetate as metal promoter. Supports and catalysts have been characterized by different techniques. Catalytic behaviour in the vapour phase for the hydrogenation of crotonaldehyde (but-2-enal) has been also analyzed. Results show that catalysts containing Rh-Sn promoted and MCM-41 as supports are, in general, more selective than the silica support. In addition, the former catalysts are more active towards the hydrogenation of the carbonyl bond to yield crotyl alcohol than the silica support.
引用
收藏
页码：1343 / 1346
页数：4
相关论文
共 50 条
  • [1] Synthesis, characterization, and catalytic properties of Al-TS-1 catalysts.
    Ban, HS
    Ko, YS
    Ahn, WS
    Hong, SB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 92 - PETR
  • [2] Mesoporous materials as supports for heteropolyacid based catalysts
    Gulbinska, M
    Wójtowski, M
    Laniecki, M
    IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B, 2002, 142 : 1221 - 1228
  • [3] Mesoporous silica based copper catalytic materials for potential deNOx application: Synthesis and characterization
    Deze, Evangelia G.
    Bareka, Maria D.
    Karousos, Dionysis S.
    Sapalidis, Andreas A.
    Favvas, Evangelos P.
    INTERNATIONAL CONFERENCES & EXHIBITION ON NANOTECHNOLOGIES, ORGANIC ELECTRONICS & NANOMEDICINE, NANOTEXNOLOGY 2020, PT 1, 2021, 54 : 1 - 6
  • [4] Mesoporous silica based copper catalytic materials for potential deNOx application: Synthesis and characterization
    Deze, Evangelia G.
    Bareka, Maria D.
    Karousos, Dionysis S.
    Sapalidis, Andreas A.
    Favvas, Evangelos P.
    MATERIALS TODAY-PROCEEDINGS, 2022, 54 : 1 - 6
  • [5] Editorial: From Mesoporous Supports to Mesoporous Catalysts: Introducing Functionality to Mesoporous Materials
    Luque, Rafael
    Garcia Martinez, Javier
    CHEMCATCHEM, 2013, 5 (04) : 827 - 829
  • [6] Synthesis, characterization and catalytic application of mesoporous sulfated zirconia
    Suh, YW
    Rhee, HK
    NANOPOROUS MATERIALS III, 2002, 141 : 289 - 296
  • [7] Synthesis, characterization and catalytic performance of ordered mesoporous Sn–Al catalysts
    Zhiwei Zhou
    Pengcheng Yu
    Juan Qin
    Wenliang Wu
    Lin Xu
    Zhiqiang Gu
    Xiaoqin Liu
    Journal of Porous Materials, 2016, 23 : 239 - 245
  • [8] Catalytic performance of micro-mesoporous materials as the supports for Pt catalysts in n-heptane isomerization
    Peyrovi, M. H.
    Parsafard, N.
    Anajafi, H. R.
    CHEMICAL PHYSICS LETTERS, 2018, 713 : 32 - 38
  • [9] Synthesis, characterization, and catalytic properties of micro-mesoporous, amorphous titanosilicate catalysts
    Keshavaraja, A
    Ramaswamy, V
    Soni, HS
    Ramaswamy, AV
    Ratnasamy, P
    JOURNAL OF CATALYSIS, 1995, 157 (02) : 501 - 511
  • [10] Synthesis, characterization and catalytic performance of ordered mesoporous Sn-Al catalysts
    Zhou, Zhiwei
    Yu, Pengcheng
    Qin, Juan
    Wu, Wenliang
    Xu, Lin
    Gu, Zhiqiang
    Liu, Xiaoqin
    JOURNAL OF POROUS MATERIALS, 2016, 23 (01) : 239 - 245
12345