On the preparation of amorphous Mg-Ni alloys by mechanical alloying

This paper deals with the preparation of the amorphous Mg-Ni alloys. By mechanical alloying (MA) the amorphous Mg-Ni alloys with different compositions have been prepared of pure elemental magnesium and nickel powder. The as-milled powder was characterized by X-ray diffraction analysis and transition electron microscope (TEM) observation. The results showed that the 30 < Ni < 70 at.% composition could be amorphized with a milling time strongly dependent on the starting chemical compositions. The investigation on the early stage of MA showed that the different compositions amorphized by two different paths. On the magnesium rich side of 30-70 at.% Ni, the as-milled powders first formed the intermetallic compound Mg2Ni, which subsequently destabilized into the amorphous phase. For the nickel rich side, the amorphous was obtained directly from the mechanical blend of magnesium and nickel powder by the suppression of the formation of thermodynamic equilibrium phase MgNi2. (C) 1999 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.