Titanium-Catalyzed Hydroaminoalkylation of Ethylene

被引：19
|
作者：
Rosien, Michael [1 ]
Toeben, Iris [1 ]
Schmidtmann, Marc [1 ]
Beckhaus, Ruediger [1 ]
Doye, Sven [1 ]
机构：
[1] Carl von Ossietzky Univ Oldenburg, Inst Chem, Carl von Ossietzky Str 9-11, D-26129 Oldenburg, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 10期
关键词：
amination; amines; ethylene; hydroaminoalkylation; titanium; C(SP(3))-H ALPHA-ALKYLATION; C-H ACTIVATION; INTERMOLECULAR HYDROAMINOALKYLATION; AMINES; TANTALUM; ALKENES; OLEFINS; REGIOSELECTIVITY; COMPLEXES; MECHANISM;
D O I：
10.1002/chem.201904502
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti-C bond of a titanaaziridine is reported.
引用
收藏
页码：2138 / 2142
页数：5
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