Synthesis and Structure of Bis- and Tris-Benzyl Bismuth Complexes

被引：9
|
作者：
Kindra, Douglas R. [1 ]
Peterson, Jeffrey K. [1 ]
Ziller, Joseph W. [1 ]
Evans, William J. [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
ORGANOMETALLICS | 2015年 / 34卷 / 01期
关键词：
RAY CRYSTAL-STRUCTURE; OXYARYL DIANION; CARBON; DERIVATIVES; ACTIVATION; REACTIVITY; INSERTION; GEOMETRY; ANTIMONY; LIGAND;
D O I：
10.1021/om5010786
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first crystallographic characterization of bismuth complexes containing benzyl ligands is reported. The NCN pincer ligand complex, Ar'BiCl2 [Ar' = 2,6-(Me2NCH2)(2)C6H3], reacts with (PhCH2)MgCl to form Ar'Bi(eta(1)-CH2Ph)(2) in high yield. X-ray crystallography and spectroscopic studies confirm eta(1)-bonding of the benzyl ligands in Ar'Bi(eta(1)-CH2Ph)(2) as well as in the homoleptic Bi(eta(1)-CH2Ph)(3).
引用
收藏
页码：395 / 397
页数：3
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