The switchable phase transition of sodium sulfate crystals activated by shock waves

被引:22
|
作者
Sivakumar, A. [1 ]
Sahaya Jude Dhas, S. [2 ]
Sivaprakash, P. [3 ]
Almansour, Abdulrahman I. [4 ]
Kumar, Raju Suresh [4 ]
Arumugam, Natarajan [4 ]
Arumugam, S. [3 ]
Martin Britto Dhas, S. A. [1 ]
机构
[1] Sacred Heart Coll, Abdul Kalam Res Ctr, Dept Phys, Shock Wave Res Lab, Tirupattur 635601, Tamil Nadu, India
[2] Kings Engn Coll, Dept Phys, Chennai 602117, Tamil Nadu, India
[3] Bharathidasan Univ, Ctr High Pressure Res, Sch Phys, Tiruchirappalli 620024, India
[4] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
关键词
HIGH-PRESSURE; FAILURE; ALUMINA;
D O I
10.1039/d1nj02974f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To date, according to the available sources obtained from a literature survey, shock-wave-induced switchable phase transitions are yet to be understood concretely as compared to irreversible phase transitions, which is probably due to a lack of understanding regarding the relationship existing between the crystal structure and shock pressure. In the present study, the switchable phase transition of sodium sulfate crystals has been formulated and demonstrated under shock conditions, and the observed switchable sequence of phase transitions is phase-V-V-III-V-V when the number of shock pulses is 0, 1, 2, 3, and 4, respectively. The above-mentioned switchable phase transition is categorically proven using diffraction, spectroscopic, and microscopic techniques, and the title material is suggested for use in switching molecules and sensor applications due to its higher shock sensitivity.
引用
收藏
页码:16529 / 16536
页数:8
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