Design of a new ultraviolet nonlinear optical material KNO3SO3NH3 exhibiting an unexpected strong second harmonic generation response

被引：34
|
作者：
Tian, Haotian. [1 ,4 ]
Lin, Chensheng [1 ]
Zhao, Xin [1 ,4 ]
Fang, Shenghao [1 ]
Li, Han [1 ,4 ]
Wang, Chao [1 ,4 ]
Ye, Ning [2 ]
Luo, Min [1 ,3 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
[2] Tianjin Univ Technol, Inst Funct Crystal, Tianjin Key Lab Funct Crystal Mat, Tianjin 300384, Peoples R China
[3] Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350002, Fujian, Peoples R China
[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
MATERIALS TODAY PHYSICS | 2022年 / 28卷
基金：
中国国家自然科学基金;
关键词：
Co -crystal engineering; Nonlinear optical materials; Theoretical calculations; Ultraviolet; Birefringence; BORATE; CRYSTALS; MECHANISM;
D O I：
10.1016/j.mtphys.2022.100849
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Based on the co-crystal engineering strategy, a new polar non-centrosymmetric compound, KNO3SO3NH3, was meticulously designed by introducing KNO3 into the centrosymmetric SO3NH3 crystal. It has an unexpected strong second-harmonic generation (SHG) response (10 x KDP), which is a new record among the inorganic nonlinear optical (NLO) materials without NLO-active cations. Theoretical calculations showed that the enhanced SHG response should be attributed to the effect of hydrogen bond. Meanwhile, it has the shortest absorption edge of 216 nm among the known materials with strong SHG responses (>8 x KDP). Besides, it possesses a large birefringence of 0.096@546 nm. Our results showed that KNO3SO3NH3 should be an excellent UV NLO crystal.
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页数：6
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