Syntheses, Structures and Photoluminescent Properties of the Two Novel Coordination Polymers [Cd(pydc)2(tu)]n and [Cd2(SO4)(nic)2(tu)1.5(H2O)2]n (pydc = Pyridine-2,3-dicarboxylate, nic = Nicotinate, tu = Thiourea)

被引：3

作者：

Xu, Chao ^{[1
,2
]}

Liu, Sheng-Bo ^{[1
,2
]}

Duan, Taike ^{[1
]}

Chen, Qun ^{[2
]}

Zhang, Qian-Feng ^{[1
,2
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Dept Appl Chem, Changzhou 213164, Jiangsu, Peoples R China

[2] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 05期

关键词：

Cadmium; Pyridine-dicarboxylate; Synthesis; Crystal Structure; Coordination Polymer; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; HYDROGEN-BONDS; LIGAND; ACID; COMPLEXES; ISONICOTINATE; CHAIN;

D O I：

10.5560/ZNB.2011.66b0459

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel cadmium coordination polymers, [Cd(pydc)(2)(tu)](n) (1) and [Cd-2(SO4)(nic)(2)(tu)(1.5)-(H2O)(2)](n) (2) (pydc = pyridine-2,3-dicarboxylate, nic = nicotinate, tu = thiourea), have been synthesized under hydrothermal conditions and structurally characterized by X-ray diffraction analysis. 1 is a one-dimensional ladder coordination polymer in a two-dimensional network formed by hydrogen bonds. 2 consists of two kinds of Cd(II) centers in different coordination environments connected via nicotinate and sulfate to form a two-dimensional grid network integrated in a three-dimensional framework generated by hydrogen bonds. 2 shows intense fluorescent emission in the solid state at room temperature.

引用

页码：459 / 464

页数：6

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[1] Syntheses, structures and photoluminescent properties of the two novel coordination polymers [Cd(pydc)2(tu)]n and [Cd 2(SO4)(nic)2(tu)1.5(H 2O)2]n (pydc = Pyridine-2,3-dicarboxylate, nic = nicotinate, tu = thiourea)
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