Mass spectrometric determination of the electron affinity of C60(CF3)10 and C60(CF3)12 molecules

被引:4
|
作者
Gruzinskaya, N. I. [1 ]
Aleshina, V. E. [1 ]
Borshchevskii, A. Ya. [1 ]
Sidorov, L. N. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
Knudsen cell mass spectrometry; electron affinity; C-60; fullerene; trifluoromethyl derivatives;
D O I
10.1134/S1061934810130046
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Knudsen cell mass spectrometry was used to study ion-molecular electron exchange reactions between some trifluoromethyl derivatives of C-60 fullerene. Electron affinity values were experimentally determined for C-60(CF3)(10) and the S (6) isomer of C-60(CF3)(12) and compared with the results of calculations and the data in the literature.
引用
收藏
页码:1328 / 1332
页数:5
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