An efficient synthesis of 8-aryl-9H-cyclopenta[a][4,7]phenanthroline derivatives catalyzed by iodine

被引：2
|
作者：
Yin, Ming-Yue [1 ]
Zhang, Mei-Mei [2 ]
Wang, Wei [1 ]
Li, Yu-Ling [1 ]
Wang, Xiang-Shan [1 ]
机构：
[1] Xuzhou Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China
[2] Xuzhou Normal Univ, Key Lab Biotechnol Med Plant Jiangsu Prov, Xuzhou 221116, Jiangsu, Peoples R China
来源：
ARKIVOC | 2011年
基金：
中国国家自然科学基金;
关键词：
Phenanthroline; quinolin-6-amine; cyclopentanone; iodine; synthesis; HIGHLY SELECTIVE METHOD; 3-ARYLBENZOQUINOLINE DERIVATIVES; COMPLEXES; 1,10-PHENANTHROLINE; COPPER(II);
D O I：
10.3998/ark.5550190.0012.b05
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of 10,11-dihydro-8-aryl-9H-cyclopenta[a][4,7]phenanthroline derivatives was prepared by a three-component reaction of aromatic aldehyde, quinolin-6-amine and cyclopentanone using iodine as catalyst. The structure of 4e is confirmed by X-ray diffraction analysis, and the crystal structure is discussed in detail. Compared to the previous method, this iodine-catalyzed procedure has the advantages of mild reaction conditions, good yields and operational simplicity.
引用
收藏
页码：51 / 59
页数：9
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