Pilot scale annular plug flow photoreactor by UV/H2O2 for the decolorization of azo dye wastewater

A pilot scale annular plug flow photoreactor with thin gap size, which combines with UV irradiation and hydrogen peroxide, was employed to deal with colored dyeing wastewater treatment. In the experiment, a mono-azo dye acid orange 10 was the target compound. The experimental parameters such as flow rate, hydrogen peroxide dosage, UV input power, pH and dye initial concentrations in a pilot scale photoreactor with flow rate of 9.32 m(3) day(-1) were investigated. Ultimately, the degradation rates were calculated and compared with a 100-1 batch reactor. In our plug flow photoreactor design, the degradation rate of acid orange 10 was 233 times higher than that of 100-1 annular batch reactor with same UV light source. The residence time needed for 99% decolorizing of 1001 of 20 mg l(-1) acid orange 10 wastewater was 26.9 min for the thin gap plug flow reactor and was far shorter than that of batch reactor needed. (c) 2005 Elsevier B.V. All rights reserved.