Characterization of Qatar's Surface Carbonates for CO2 Capture and Thermochemical Energy Storage

Samples of surface carbonates were collected from three different areas of the Qatar peninsula. We employed material characterization techniques to examine the morphology and composition of the samples, while their CO2 capture capacity was assessed via multiple successive calcination-carbonation cycles. Our samples were mainly calcite and dolomite based. Calcite samples showed higher initial capacity of around 11 mmol CO2 g(-1) which decayed rapidly to less than 2 mmol CO2 g(-1). On the other hand, dolomite samples showed an excellent stability (similar to 15 cycles) with a capacity of 6 mmol CO2 g(-1). The performance of the dolomite samples is better compared to other similar natural samples, from literature. A promising result for future studies towards improving their performance by physical and chemical modification.