Reactions of N-nitramines and their trimethylsilyl derivatives with N,N-bis(trimethylsilyloxy)enamines

被引：6
|
作者：
Ioffe, SL [1 ]
Makarenkova, LM [1 ]
Strelenko, YA [1 ]
Bliznets, IV [1 ]
Tartakovsky, VA [1 ]
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
nitramines; silylation; N; C-cross-coupling; N-bis(trimethylsilyloxy)enamines;
D O I：
10.1007/BF02494513
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Trimethylsilyl derivatives of methyl- and ethylnitramine react as N-centered nucleophiles with 2-N,N-bis(trimethylsilyloxy)aminopropene to give trimethylsilyl derivatives of hitherto unknown alpha-(N-nitro)alkylamino-substituted acetone oximes. As an ambident nucleophile, nonsubstituted methylnitramine reacts with the same enamine to give both a product of N,C-cross-coupling and a product of O,C-cross-coupling, viz., N'-methyl-N-[(2-trimethylsilyloxyimino)propoxy]diazene N-oxide.
引用
收藏
页码：1989 / 1991
页数：3
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