Production of 5-Hydroxymethylfurfural from Cellulose Catalyzed by Lewis Acid under Microwave Irradiation in Ionic Liquid

被引:6
|
作者
Wu Shuchang [1 ,2 ]
Wang Chunlei [1 ]
Gao Yongjun [1 ,2 ]
Zhang Shaochun [3 ]
Ma Ding [1 ]
Zhao Zongbao [1 ,4 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Dalian Univ Technol, Sch Chem Engn, Dalian 116023, Liaoning, Peoples R China
[4] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
关键词
ionic liquid; microwave; Lewis acid; cellulose; 5-hydroxymethylfurfural; FRUCTOSE; DEHYDRATION; CONVERSION; BIOMASS; CHEMISTRY; SUGARS; FURANS; FUELS;
D O I
10.3724/SP.J.1088.2010.00149
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Direct conversion of cellulose into 5-hydroxymethylfurfural (HMF) catalyzed by CrCl3 6H(2)O in ionic liquid 1-butyl-3-methylimidazolium chloride ([bmim]Cl) was described with the promotion of microwave The effects of microwave irradiation setting, reaction temperature. reaction time, and catalyst amount on HMF yield were investigated The results showed that cellulose was converted into HMF rapidly and efficiently in [bmim]Cl with the HMF yield of 55%
引用
收藏
页码:1157 / 1161
页数:5
相关论文
共 25 条
  • [1] Preparation of 5-hydroymethylfurfural by dehydration of fructose in the presence of acidic ionic liquid
    Bao, Quanxi
    Qiao, Kun
    Tomida, Daisuke
    Yokoyama, Chiaki
    [J]. CATALYSIS COMMUNICATIONS, 2008, 9 (06) : 1383 - 1388
  • [2] Dehydration of D-fructose to hydroxymethylfurfural in sub- and supercritical fluids
    Bicker, M
    Kaiser, D
    Ott, L
    Vogel, H
    [J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2005, 36 (02): : 118 - 126
  • [3] Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals
    Binder, Joseph B.
    Raines, Ronald T.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) : 1979 - 1985
  • [4] Burrell AK, 2007, GREEN CHEM, V9, P809, DOI 10.1039/b615950h
  • [5] Selective Conversion of Fructose to 5-Hydroxymethylfurfural Catalyzed by Tungsten Salts at Low Temperatures
    Chan, Jin Young Gerentt
    Zhang, Yugen
    [J]. CHEMSUSCHEM, 2009, 2 (08) : 731 - 734
  • [6] Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides
    Chheda, Juben N.
    Roman-Leshkov, Yuriy
    Dumesic, James A.
    [J]. GREEN CHEMISTRY, 2007, 9 (04) : 342 - 350
  • [7] THE USE OF MICROWAVE-OVENS FOR RAPID ORGANIC-SYNTHESIS
    GEDYE, R
    SMITH, F
    WESTAWAY, K
    ALI, H
    BALDISERA, L
    LABERGE, L
    ROUSELL, J
    [J]. TETRAHEDRON LETTERS, 1986, 27 (03) : 279 - 282
  • [8] Conversion of fructose to 5-hydroxymethylfurfural using ionic liquids prepared from renewable materials
    Hu, Suqin
    Zhang, Zhaofu
    Zhou, Yinxi
    Han, Buxing
    Fan, Honglei
    Li, Wenjing
    Song, Jinliang
    Xie, Ye
    [J]. GREEN CHEMISTRY, 2008, 10 (12) : 1280 - 1283
  • [9] Dehydration of fructose into 5-hydroxymethylfurfural in the presence of ionic liquids
    Lansalot-Matras, C
    Moreau, C
    [J]. CATALYSIS COMMUNICATIONS, 2003, 4 (10) : 517 - 520
  • [10] Direct conversion of glucose and cellulose to 5-hydroxymethylfurfural in ionic liquid under microwave irradiation
    Li, Changzhi
    Zhang, Zehui
    Zhao, Zongbao K.
    [J]. TETRAHEDRON LETTERS, 2009, 50 (38) : 5403 - 5405