C-H Bond Cleavage and Regioselective C-C Coupling on a Tantalum-Bound Pincer Ligand

被引：8

作者：

Conde, Ana ^{[1
]}

Fandos, Rosa ^{[1
]}

Hernandez, Carolina ^{[1
]}

Otero, Antonio ^{[2
]}

Rodriguez, Ana ^{[3
]}

机构：

[1] Univ Castilla La Mancha, Inst Nanociencia Nanotecnol & Mat Mol INAMOL, Fac Ciencias Medio Ambiente, Dept Quim Inorgan Organ & Bioquim, Toledo 45071, Spain

[2] Univ Castilla La Mancha, Fac Quim, Dept Quim Inorgan Organ & Bioquim, E-13071 Ciudad Real, Spain

[3] Univ Castilla La Mancha, ETS Ingenieros Ind, Dept Quim Inorgan Organ & Bioquim, E-13071 Ciudad Real, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 40期

关键词：

C-C coupling; C-H activation; organometallic complexes; pincer ligands; tantalum; COMPLEXES; CRYSTAL-STRUCTURE; CARBON-MONOXIDE CLEAVAGE; ALKYNE COMPLEXES; ACTIVATION; REACTIVITY; FUNCTIONALIZATION; PYRIDINE; MODELS; REARRANGEMENT; DERIVATIVES;

D O I：

10.1002/chem.201001555

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cleavage and coupling: The sequential C-H activation/C-C coupling processes on a tantalum-bound pincer ligand render a variety of tetradentate ligands (see scheme). © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12074 / 12078

页数：5

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