Palladium-catalyzed carbonylative coupling of organolead compounds: Synthesis of symmetrical ketones

被引:7
|
作者
Kang, SK [1 ]
Ryu, HC [1 ]
Choi, SC [1 ]
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 400746, South Korea
关键词
D O I
10.1081/SCC-100103533
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Organolead acetates can be carbonylated in the presence of Pd-2(dba)(3). CHCl3 (5 mol%) and NaOMe (5 equiv.) in CH3CN under atmospheric pressure of carbon monoxide at room temperature to afford symmetrical ketones.
引用
收藏
页码:1035 / 1039
页数:5
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