Comparative studies of the mechanical and thermal properties of clay/copolymer nanocomposites synthesized by two in-situ methods and solution blending method

被引:6
|
作者
Hernandez-Guerrero, Oscar [1 ,2 ]
Fabian Campillo-Illanes, Bernardo [2 ,3 ]
Lilia Dominguez-Patino, Martha [1 ]
Benavente, Rosario [4 ]
Martinez, Horacio [2 ,3 ]
Sedano, Alejandro [1 ]
Villanueva, Heriberto [1 ]
机构
[1] Univ Autonoma Estado Mexico, Ctr Univ Tenancingo, Fac Ciencias Quim & Ingn, Ave Univ 1001, Cuernavaca 62209, Morelos, Mexico
[2] UNAM, ICF, Cuernavaca, Morelos, Mexico
[3] UNAM, FQ, Ciudad De Mexico, Mexico
[4] CSCI, Inst Ciencia & Tecnol Polimeros, Madrid, Spain
关键词
In-situ; Nanocomposites; Exfoliation; Intercalation; SILICATE NANOCOMPOSITES; CLAY; MORPHOLOGY; ADHESIVES;
D O I
10.1007/s10965-019-1966-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, copolymer/clay nanocomposites were prepared by two different methodologies, the in-situ method and solution blending method. Comparative analyses of mechanical and thermal properties of the nanocomposites fabricated by the two different methods were performed. The solution blending method was found to be an efficient technique to obtain nanocomposites with uniform dispersion of the organoclay loading of up to 10 wt%, simple and fast. On the other hand, the in-situ method produced nanocomposites with good exfoliation and high thermal stability, whereas solution blending method produced materials with good mechanical properties compounds in the nano/clay intercalation and high thermal stability.
引用
收藏
页数:7
相关论文
共 50 条
  • [1] Comparative studies of the mechanical and thermal properties of clay / copolymer nanocomposites synthesized by two in-situ methods and solution blending method
    Oscar Hernández-Guerrero
    Bernardo Fabián Campillo-Illanes
    Martha Lilia Domínguez-Patiño
    Rosario Benavente
    Horacio Martínez
    Alejandro Sedano
    Heriberto Villanueva
    [J]. Journal of Polymer Research, 2020, 27
  • [2] Comparative studies of the morphological and thermal properties of clay/polymer nanocomposites synthesized via melt blending and modified solution blending methods
    Dlamini, D. S.
    Mishra, S. B.
    Mishra, A. K.
    Mamba, B. B.
    [J]. JOURNAL OF COMPOSITE MATERIALS, 2011, 45 (21) : 2211 - 2216
  • [3] Thermo-mechanical Properties of Copolymer/Clay Nanocomposites: A Comparative Study of Production Method by In-situ and Solution Mixture
    Hernandez-Guerrero, Oscar
    Castillo-Perez, Ruben
    Lizbeth Hernandez-Vargas, Mireya
    Fabian Campillo-Illanes, Bernardo
    [J]. PROCEEDINGS OF THE 3RD PAN AMERICAN MATERIALS CONGRESS, 2017, : 457 - 464
  • [4] Study Of Thermal And Mechanical Properties Of Clay/Polymer Nanocomposite Synthesized Via Modified Solution Blending
    Oscar Hernandez-Guerrero
    Rubén Castillo-Pérez
    Mireya Lizbeth Hernández-Vargas
    Bernardo Fabián Campillo-Illanes
    [J]. MRS Advances, 2017, 2 (49) : 2757 - 2762
  • [5] In-situ synthesized poly(vinyl butyral)/MMT-clay nanocomposites: The role of degree of acetalization and clay content on thermal, mechanical and permeability properties of PVB matrix
    Saravanan, S.
    Gowda, K. M. Akshay
    Varman, K. Arul
    Ramamurthy, Praveen C.
    Madras, Giridhar
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2015, 117 : 417 - 427
  • [6] Preparation and properties of new in-situ acrylic copolymer/terpolymer-clay hybrid nanocomposites
    Patel, S.
    Bandyopadhyay, A.
    Vijaybaskar, V.
    Bhowmick, Anil K.
    [J]. RUBBER CHEMISTRY AND TECHNOLOGY, 2006, 79 (05): : 820 - 834
  • [7] Studies on thermal and mechanical properties of polyimide-clay nanocomposites
    Agag, T
    Koga, T
    Takeichi, T
    [J]. POLYMER, 2001, 42 (08) : 3399 - 3408
  • [8] Investigation of in situ prepared polypropylene/clay nanocomposites properties and comparing to melt blending method
    Baniasadi, H.
    Ramazani S. A., A.
    Nikkhah, S. Javan
    [J]. MATERIALS & DESIGN, 2010, 31 (01) : 76 - 84
  • [9] Morphology and properties of poly(methyl methacrylate)/clay nanocomposites by in-situ solution polymerization
    Tsai, Tsung-Yen
    Lin, Mei-Ju
    Chang, Ching-Wen
    Li, Chen-Chi
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2010, 71 (04) : 590 - 594
  • [10] Characterization and comparison of thermal & mechanical properties of vermiculite polyvinylbutyral nanocomposites synthesized by solution casting method
    Isci, Sevim
    Isci, Yavuz
    [J]. APPLIED CLAY SCIENCE, 2018, 151 : 189 - 193