Recent advances in the application of deep eutectic solvents as sustainable media as well as catalysts in organic reactions

被引：518

作者：

Liu, Peng ^{[1
]}

Hao, Jian-Wu ^{[1
]}

Mo, Li-Ping ^{[1
]}

Zhang, Zhan-Hui ^{[1
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China

来源：

RSC ADVANCES | 2015年 / 5卷 / 60期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; FISCHER INDOLE SYNTHESIS; N-SUBSTITUTED PYRROLES; LOW-MELTING MIXTURES; UREA-SALT MIXTURES; 3-COMPONENT COMBINATORIAL SYNTHESIS; MAGNETICALLY SEPARABLE CATALYST; MICROWAVE-ASSISTED SYNTHESIS; 4-COMPONENT DOMINO PROTOCOL; HIGHLY EFFICIENT SYNTHESIS;

D O I：

10.1039/c5ra05746a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deep eutectic solvents (DESs), also known as deep eutectic ionic liquids (DEILs) or low-melting mixtures (LMMs) or low transition temperature mixtures (LTTMs) in the literature, have become more and more attractive in recent years due to their interesting properties and benefits, such as low cost of components, easy to prepare, tunable physicochemical properties, negligible vapor pressure, nontoxicity, biorenewability and biodegradability. These eutectic mixtures have been widely used as green and sustainable media as well as catalysts in many chemical processes. This review focuses on recent advances using DESs in organic reactions including addition reactions, cyclization reactions, replacement reactions, multicomponent reactions, condensation reactions, oxidation reactions, and reducing reactions.

引用

页码：48675 / 48704

页数：30

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