The structural chemistry of triorganotin(IV) derivatives of 3-amino-5-mercapto-1,2,4-triazole:: Supramolecular structures involving intermolecular N-H•••N and N-H•••S hydrogen bonding

被引：11
|
作者：
Ma, Chunlin [1 ,2 ]
Li, Yongxin [1 ]
Han, Yawen [1 ]
Zhang, Rufen [1 ]
机构：
[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China
[2] Taishan Univ, Tai An 271021, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 01期
基金：
中国国家自然科学基金;
关键词：
triorganotin(IV); 3-amino-5-mercapto-1,2,4-triazole; hydrogen bonding;
D O I：
10.1016/j.ica.2007.06.045
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new triorganotin complexes of 3-amino-5-mercapto-1,2,4-triazole with the type of R3Sn(SC2N3HNH2-3) (R = Me, 1; n-Bu, 2; Ph, 3; PhCH2, 4) have been synthesized. All the complexes have been characterized by elemental analysis, IR, H-1 NMR and C-13 NMR spectra. Complexes 1, 3 and 4 have been characterized by X-ray crystallography analyses too. The geometry about Sn of complex I is distorted trigonal bipyramidal and the supramolecular structures of complex 1 has been found consist of channels built up by intermolecular N-H center dot center dot center dot N hydrogen bonding. The geometry of tin atoms in complexes 3 and 4 are distorted tetrahedron and I D polymers connected by intermolecular N-H center dot center dot center dot N hydrogen bonding or N-H center dot center dot center dot N and N-H center dot center dot center dot S hydrogen bonding. Additionally, ID polymer of complex 3 aggregated in 2D layer by intermolecular N-H center dot center dot center dot S hydrogen bonding. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：380 / 386
页数：7
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