Microstructure and mechanical properties of in situ synthesized alumina/Ba-β-alumina/zirconia composites

被引:19
|
作者
Chen, ZC
Chawla, KK
Koopman, M
机构
[1] Univ Alabama, Dept Mat Sci & Engn, Birmingham, AL 35294 USA
[2] Tohoku Univ, Sch Engn, Dept Mat Proc, Aoba Ku, Sendai, Miyagi 9808579, Japan
关键词
in situ synthesis; Ba-beta-alumina; elongated particles; barium zirconate; ceramic matrix composites;
D O I
10.1016/j.msea.2003.09.070
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A new alumina matrix composite has been synthesized via in situ reactive sintering of Al2O3 and BaZrO3 powders. Phases formed in situ were Ba-beta-Al2O3 (BaO(.)7.3Al(2)O(3)) (a so-called hexaaluminate compound) with a layered beta-Al2O3 structure and monoclinic ZrO2. The Ba-beta-Al2O3 phase exhibited an elongated morphology, while ZrO2 was primarily present in an equiaxed form. Composites of Ba-beta-Al2O3, ZrO2 and alumina encouraged crack deflection and crack bridging, thus improving the mechanical properties beyond those of monolithic alumina. The alumina-based composite with 30% Ba-beta-Al2O3 and ZrO2 showed an optimum combination of mechanical properties: high strength, large work of fracture, and improved fracture toughness. (C) 2003 Published by Elsevier B.V.
引用
收藏
页码:24 / 32
页数:9
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