Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite

被引：55

作者：

Khitev, Yu P. ^{[1
]}

Kolyagin, Yu G. ^{[1
,2
]}

Ivanova, I. I. ^{[1
,2
]}

Ponomareva, O. A. ^{[1
,2
]}

Thibault-Starzyk, F. ^{[3
]}

Gilson, J-P ^{[3
]}

Fernandez, C. ^{[3
]}

Fajula, F. ^{[4
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119892, Russia

[2] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia

[3] Univ Caen, CNRS, ENSICAEN, Catalyse & Spectrochim Lab, F-14050 Caen, France

[4] ENSCM, Inst Charles Gerhardt Montpellier, CNRS, UMR 5253,UM2, F-34296 Montpellier, France

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2011年 / 146卷 / 1-3期

关键词：

Ferrierite; Micro/mesoporous catalysts; Zeolites; MESOPOROUS MATERIALS; SKELETAL ISOMERIZATION; DELAMINATED ZEOLITES; ACID SITES; ACCESSIBILITY; FERRIERITE; RECRYSTALLIZATION; COMPOSITES; LOCATION; BUTENE;

D O I：

10.1016/j.micromeso.2011.05.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Hierarchical zeolitic catalysts with varying ratios of micro- and mesoporosity were prepared by recrystallization of ferrierite (FER) in alkaline solution in the presence of cetyltrimethylammonium bromide. The catalysts were characterized by XRD, TPD-NH3, Fr-IR, nitrogen adsorption-desorption, SEM, TEM. The influence of alkali concentration on the distribution of micro- and mesopores is discussed. The recrystallization process led to a significant increase of accessibility of the acid sites, together with a decrease of the total acidity. The catalytic properties were investigated in 1-butene isomerization. All recrystallized materials showed improved catalytic activity and selectivity in isomerization. (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：201 / 207

页数：7

共 50 条

[1] Physicochemical and Catalytic Properties of Micro-Mesoporous Zeolite Materials
Ponomareva, O. A.
Timoshin, S. E.
Knyazeva, E. E.
Ordomskii, V. V.
Yushchenko, V. V.
Kulikov, N. S.
Zaikovskii, V. I.
Ivanova, I. I.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (12) : 2103 - 2108
[2] Physicochemical and catalytic properties of micro-mesoporous zeolite materials
O. A. Ponomareva
S. E. Timoshin
E. E. Knyazeva
V. V. Ordomskii
V. V. Yushchenko
N. S. Kulikov
V. I. Zaikovskii
I. I. Ivanova
Russian Journal of Physical Chemistry A, 2011, 85 : 2103 - 2108
[3] Skeletal isomerization of 1-butene over micro/mesoporous materials based on FER zeolite
Khitev, Yu. P.
Ivanova, I. I.
Kolyagin, Yu. G.
Ponomareva, O. A.
APPLIED CATALYSIS A-GENERAL, 2012, 441 : 124 - 135
[4] Micro-mesoporous materials obtained by zeolite recrystallization: synthesis, characterization and catalytic applications
Ivanova, Irina I.
Knyazeva, Elena E.
CHEMICAL SOCIETY REVIEWS, 2013, 42 (09) : 3671 - 3688
[5] Transport properties of hierarchical micro-mesoporous materials
Schneider, Daniel
Mehlhorn, Dirk
Zeigermann, Philipp
Kaerger, Joerg
Valiullin, Rustem
CHEMICAL SOCIETY REVIEWS, 2016, 45 (12) : 3439 - 3467
[6] Synthesis of Hierarchical Micro-mesoporous ZSM-5 Zeolite and its Catalytic Activity in Benzylation of Mesitylene
Manikandan Krishnamurthy
M. Swaminathan
Silicon, 2023, 15 : 3399 - 3405
[7] Synthesis of Hierarchical Micro-mesoporous ZSM-5 Zeolite and its Catalytic Activity in Benzylation of Mesitylene
Krishnamurthy, Manikandan
Swaminathan, M.
SILICON, 2023, 15 (08) : 3399 - 3405
[8] Design of hierarchical micro-mesoporous materials for different catalytic applications using surfactant-mediated zeolite recrystallization
Ivanova, Irina I.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[9] Synthesis, Characterization and Catalytic Applications of Hierarchical Pore Zeolite Materials
Wang Yang
Ma Liyong
Zhu Ning
Chen Fengqiu
Zhan, Xiaoli
PROGRESS IN CHEMISTRY, 2009, 21 (09) : 1722 - 1733
[10] Amino-Acid-Assisted Synthesis of Hollow Hierarchical FER Zeolite with Improved Catalytic Performance
Jiao, Feng
Li, Hao
Hu, Qing
Xu, Yanan
Guo, Hailing
Du, Hongbin
CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (62)

← 1 2 3 4 5 →