Synthesis and redox behavior of benzo-1,3-dithiafulvalenes incorporating ferrocene moiety as redox active ligands

被引：7

作者：

Sarhan, AE ^{[1
]}

Izumi, T ^{[1
]}

机构：

[1] Yamagata Univ, Fac Engn, Dept Chem & Chem Engn, Yonezawa, Yamagata 9928510, Japan

来源：

SYNTHETIC METALS | 2004年 / 140卷 / 01期

关键词：

Fc-DTF; synthesis; organic conducting materials; electrochemical properties;

D O I：

10.1016/S0379-6779(03)00383-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A simple route for the synthesis of several new benzo-1,3-dithiafulvalenes incorporated with ferrocene (Fc) moiety is reported. The benzo-1,3-dithiafulvalenes (6a-f) were synthesized by introducing a ferrocene coordination function as new donor compounds based on the Wittig-Horner olefenation method. The redox behavior of the new donor compounds was investigated in comparison with the ferrocene and established 1,4-dithiafulvalenes by cyclic voltammetry. Two couples of redox peaks were observed for both ferrocene and extended dithiafulvalene (DTF). (C) 2003 Elsevier B.V. All rights reserved.

引用

下载

页码：95 / 100

页数：6

共 50 条

[1] Synthesis and redox behavior of new ferrocene-π-extended-dithiafulvalenes: An approach for anticipated organic conductors
Sarhan, Abdelwareth A. O.
Mohammed, Omar F.
Izumi, Taeko
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2009, 5
[2] Redox behavior of ferrocene-containing rotaxane: Transposition of the rotaxane wheel by redox reaction of a ferrocene moiety tethered at the end of the axle
Kihara, N
Hashimoto, M
Takata, T
ORGANIC LETTERS, 2004, 6 (11) : 1693 - 1696
[3] Linear oligopyrroles as redox-active ligands: Metal coordination and redox behavior
Tomat, Elisa
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
[4] SYNTHESIS AND CHARACTERIZATION OF RHENIUM COMPLEXES HAVING LIGANDS CONTAINING REDOX ACTIVE FERROCENE - OXIDATIVELY TUNABLE COMPLEXES
MILLER, TM
WRIGHTON, MS
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 351 - INOR
[5] Switchable magnetic materials incorporating redox active bridging ligands.
Melman, JH
Emge, TJ
Gordon-Wylie, SW
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U849 - U849
[6] Synthesis and nonvolatile memory behavior of redox-active conjugated polymer-containing ferrocene
Choi, Tae-Lim
Lee, Kwang-Hee
Joo, Won-Jae
Lee, Sangkyun
Lee, Tae-Woo
Chae, Mi Young
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (32) : 9842 - +
[7] SYNTHESIS AND REDOX BEHAVIOR OF HIGHLY CONJUGATED BIS(BENZO-1,3-DITHIOLE) AND BIS(BENZOTHIAZOLE) SYSTEMS CONTAINING AROMATIC LINKING GROUPS - MODEL SYSTEMS FOR ORGANIC METALS
BRYCE, MR
FLECKENSTEIN, E
HUNIG, S
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (11): : 1777 - 1783
[8] Cyclic Naphthalene Diimide with a Ferrocene Moiety as a Redox-Active Tetraplex-DNA Ligand
Kaneyoshi, Shuma
Zou, Tingting
Ozaki, Shunsuke
Takeuchi, Ryusuke
Udou, Ayano
Nakahara, Takumi
Fujimoto, Kazuhisa
Fujii, Satoshi
Sato, Shinobu
Takenaka, Shigeori
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (01) : 139 - 142
[9] Synthesis and characterization of redox-active coordination polymers generated from ferrocene-containing bridging ligands
Horikoshi, R
Mochida, T
Moriyama, H
INORGANIC CHEMISTRY, 2002, 41 (11) : 3017 - 3024
[10] Facile Post-synthesis and Redox Behavior of π-Expanded Ferrocene and ansa-Ferrocene
Morimoto, Hirofumi
Matsuo, Kyohei
Hayashi, Hironobu
Yamada, Hiroko
Aratani, Naoki
CHEMISTRY LETTERS, 2022, 51 (04) : 428 - 430

← 1 2 3 4 5 →