New 2-azanorbornyl derivatives: chiral (N,N)-donating ligands for asymmetric catalysis

被引:6
|
作者
Wojaczynska, Elzbieta [1 ]
机构
[1] Wroclaw Univ Technol, Dept Organ Chem, Fac Chem, PL-50370 Wroclaw, Poland
关键词
ENANTIOSELECTIVE HENRY REACTION; TRANSFER HYDROGENATION; ALLYLIC ALCOHOLS; ACID-DERIVATIVES; COMPLEXES; ISOMERIZATION; REARRANGEMENT; DIETHYLZINC; EPOXIDATION; EPOXIDES;
D O I
10.1016/j.tetasy.2010.12.011
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New chiral 2-azanorbornane derivatives were prepared and used as (N,N)-donating ligands in a copper-catalyzed Henry reaction yielding up to 62% ee. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:161 / 166
页数:6
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