Y/composite titania-silica (CTS) supported catalyst for hydrotreating coker gas oil

Y/composite titania-silica (CTS) support was prepared by the in situ growth of CTS on HY zeolite. The effects of HY zeolite pretreatment Y/CTS modification with P and F for adjusting the acidity of the support were studied. The results showed that the structure of Y/CTS was in form of CTS as shell and HY zeolite particles as core. The content of HY zeolite affected the acidity, acidity distribution and pore structure Y/CTS. The density of strong acid sites on the HY zeolite surface could be partly reduced by dealumination with citric acid. This reduced the coverage on the outer surface of the HY zeolite, leading to the increased acidity of Y/CTS. The acidity distribution of the support could also adjusted by P and F modification. Hydrotreating catalysts were prepared with Y/CTS as support. The catalysts were tested using the reaction of a coker gas oil (CGO). The experimental results showed that the catalyst hydrodenitrogenation (HDN) performance could remarkably improved by adjusting the acidity of the catalyst support via HY zeolite pretreatment and P and F modification. The catalysts proper Bronsted (B) acidity and Lewis (L) acidity behaved well in hydrodesulfurization (HDS) and HDN performances. (C) 2007 Elsevier B.V. All rights reserved.