Magnetic Control over the Fractal Dimension of Supramolecular Rod Networks

被引：5

作者：

Marichez, Vincent ^{[1
]}

Sato, Akihiro ^{[1
]}

Dunne, Peter A. ^{[1
]}

Leira-Iglesias, Jorge ^{[1
]}

Formon, Georges J. M. ^{[1
]}

Schicho, Michaela K. ^{[1
]}

de Feijter, Isja ^{[2
]}

Hebraud, Pascal ^{[3
]}

Bailleul, Matthieu ^{[3
]}

Besenius, Pol ^{[4
]}

Venkatesan, Munuswamy ^{[5
]}

Coey, J. M. D. ^{[5
]}

Meijer, E. W. ^{[2
]}

Hermans, Thomas M. ^{[1
]}

机构：

[1] Univ Strasbourg, F-67083 Strasbourg, France

[2] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

[3] Univ Strasbourg, Inst Phys & Chim Mat Strasbourg, F-67034 Strasbourg, France

[4] Johannes Gutenberg Univ Mainz, Dept Chem, D-55128 Mainz, Germany

[5] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2021年 / 143卷 / 31期

基金：

爱尔兰科学基金会;

关键词：

DISCOTIC AMPHIPHILES; POLYMERS; PH;

D O I：

10.1021/jacs.1c05053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlling supramolecular polymerization is of fundamental importance to create advanced materials and devices. Here we show that the thermodynamic equilibrium of Gd3+-bearing supramolecular rod networks is shifted reversibly at room temperature in a static magnetic field of up to 2 T. Our approach opens opportunities to control the structure formation of other supramolecular or coordination polymers that contain paramagnetic ions.

引用

页码：11914 / 11918

页数：5

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