Thallium(I)-selective membrane potentiometric sensor based on dibenzyldiaza-18-crown-6

被引:0
|
作者
Khayatian, G [1 ]
Shariati, S [1 ]
Salimi, A [1 ]
机构
[1] Kurdistan Univ, Dept Chem, Sanandaj, Iran
关键词
thallium ion-selective electrode; PVC membrane; potentiometry;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new thallium(l) selective electrode based on dibenzyldiaza-18-crown-6 as membrane carrier was successfully prepared. The electrode exhibits a near-Nernstian response for Tl+ ions over a wide concentration range from 1.0 X 10(-5)-1.0X10(-1) M at 25 degreesC, and was found to be selective, precise and useable within the pH range 4.0-11.0. The electrode was successfully used as an indicator electrode in potentiometric titration of thallium ions.
引用
收藏
页码:421 / 425
页数:5
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