A new heptadentate tripodal ligand leading to a gadolinium complex with an improved relaxation efficiency

被引:45
|
作者
Bretonnière, Y
Mazzanti, M [1 ]
Pécaut, J
Dunand, FA
Merbach, AE
机构
[1] CEA Grenoble, Dept Rech Fondamentale Mat Condensee, Serv Chim Inorgan & Biol,Serv Chim Inorgan & Biol, Lab Reconnaissance Ion & Mat Mol,UMR 5046, F-38054 Grenoble 09, France
[2] CEA Grenoble, Dept Rech Fondamentale Mat Condensee, Chim Coordinat Lab, Serv Chim Inorgan & Biol,UMR 5046, F-38054 Grenoble, France
[3] Univ Lausanne, BCH, Inst Chim Minerale & Analyt, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1039/b100657f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new heptadentate tripodal ligand tpaa containing three pyridinecarboxylate binding units reacts with Cd(III) in water to give a thermodynamically stable complex which displays high relaxivity.
引用
收藏
页码:621 / 622
页数:2
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