Tetrakis(μ-phenoxyacetato-κ2O:O′ )bis[(1,10-phenanthroline-κ2N,N′)-manganese(II)] methanol hemisolvate

被引：3

作者：

Wu, Dong-Hui ^{[1
]}

Shi, Jian ^{[1
]}

Shi, Yu-Jun ^{[1
]}

Jiang, Guo-Qing ^{[1
]}

机构：

[1] Nantong Univ, Coll Chem & Chem Engn, Nantong 226019, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536807065269

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Mn-2(C8H7O3)(4)(C12H8N2)(2)]center dot 0.5CH(3)OH, is a carboxylate-bridged dinuclear Mn-II complex with four phenoxyacetate ions and two 1,10-phenanthroline molecules as ligands. Each of the four phenoxyacetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent molecule. Face-to-face pi-pi stacking interactions between the aromatic rings of 1,10-phenanthroline molecules belonging to adjacent Mn-2 complexes, with an interplanar separation of circa 3.4 angstrom, and weak C-H center dot center dot center dot O hydrogen bonds connect the dinuclear units into a three-dimensional supramolecular framework.

引用

页码：M161 / U1530

页数：17

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