Nickel-Catalyzed Ring-Opening Three-Component Coupling of Methylenecyclopropane with Aldehydes and Silanes

被引：34
|
作者：
Ogata, Kenichi [1 ]
Atsuumi, Yuka [1 ]
Fukuzawa, Shin-ichi [1 ]
机构：
[1] Chuo Univ, Dept Appl Chem, Inst Sci & Engn, Bunkyo Ku, Tokyo 1128551, Japan
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 20期
关键词：
ETHYL CYCLOPROPYLIDENEACETATE; ALKYNES; CYCLOADDITION; OLEFINS; LIGAND;
D O I：
10.1021/ol101838q
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A nickel-catalyzed three-component coupling between methylenecyclopropane, aldehydes, and silanes afforded silylated allylic alcohols that possess an alkyl substituent at the 2-position via cleavage of the proximal C-C bond of methylenecyclopropane
引用
收藏
页码：4536 / 4539
页数：4
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