On the interactions of phenol, aniline and p-nitrophenol on activated carbon surfaces as detected by TPD

被引:28
|
作者
Castillejos-Lopez, Eva [1 ]
Nevskaia, Daniela M. [1 ]
Munoz, Vicenta [1 ]
Guerrero-Ruiz, Antonio [1 ]
机构
[1] Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan & Quim Tecn, E-28040 Madrid, Spain
关键词
D O I
10.1016/j.carbon.2008.02.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The interactions of phenol, aniline and p-nitrophenol, adsorbed from aqueous solutions, with the surface of two activated carbons (with and without oxygen surface groups) were followed by temperature programmed desorption, thermogravimetry and analysis by mass spectrometry. The results reveal that on bare surface the three molecules can be presented as physisorbed and chemisorbed species. When oxygen surface groups are introduced on the carbon surface, there is a change in the adsorption/desorption behaviour; in such a way that the phenol chemisorption is inhibited and that decomposition of aniline and nitrophenol are originated. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:870 / 875
页数:6
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