ZnO and ZnO-nanoparticles: Efficient and reusable heterogeneous catalysts for one-pot synthesis of N-acylsulfonamides and sulfonate esters

被引:40
|
作者
Tamaddon, Fatemeh [1 ]
Sabeti, Mohammad Reza [1 ]
Jafari, Abbas Ali [1 ]
Tirgir, Farhang [1 ]
Keshavarz, Elham [1 ]
机构
[1] Yazd Univ, Dept Chem, Fac Sci, Yazd 89195741, Iran
关键词
N-acylsulfonamides; Amines; Sulfonylation; Acylation; ZnO; Sulfonate esters; Sulfonamides; SOLVENT-FREE; O-ACYLATION; ALCOHOLS; MILD; AMINES; MONOSULFONYLATION; SULFONYLATION; UREAS; OXIDE; ACID;
D O I
10.1016/j.molcata.2011.09.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Commercially available and preparative ZnO nanoparticles are reported as efficient and reusable catalysts for the chemoselective synthesis of N-acylsulfonamides and sulfonate esters. A one-pot sequential sulfonylation and acylation of amines took place to afford the N-acylsulfonamides in excellent yields under solvent-free conditions. The ZnO catalyst can be reused for without significant loss of catalytic activity. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:41 / 45
页数:5
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