Material Flows of Polyurethane in the United States

被引:58
|
作者
Liang, Chao [1 ]
Gracida-Alvarez, Ulises R. [2 ]
Gallant, Ethan T. [2 ,3 ]
Gillis, Paul A. [4 ]
Marques, Yuri A. [4 ]
Abramo, Graham P. [5 ]
Hawkins, Troy R. [2 ]
Dunn, Jennifer B. [6 ,7 ]
机构
[1] Northwestern Univ, Inst Sustainabil & Energy Northwestern, Evanston, IL 60208 USA
[2] Argonne Natl Lab, Energy Syst Div, Syst Assessment Ctr, Lemont, IL 60439 USA
[3] Univ Minnesota, Bioprod & Biosyst Engn, St Paul, MN 55108 USA
[4] Dow Chem Co USA, Polyurethane R&D, Lake Jackson, TX 77566 USA
[5] Dow Chem Co USA, Core Res & Dev, Collegeville, PA 19426 USA
[6] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[7] Northwestern Argonne Inst Sci & Engn, Evanston, IL 60208 USA
关键词
polyurethane; material flow analysis; recycling; circular economy; biobased feedstock; sustainability; RECOVERY;
D O I
10.1021/acs.est.1c03654
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Today, polyurethanes are effectively not recycled and are made principally from nonrenewable, fossil-fuel-derived resources. This study provides the first high-resolution material flow analysis of polyurethane flows through the U.S. economy, tracking back to fossil fuels and covering polyurethane-relevant raw materials, trade, production, manufacturing, uses, historical stocks, and waste management. According to our analysis, in 2016, 2900 thousand tonnes (kt) of polyurethane were produced in the United States and 920 kt were imported for consumption, 2000 kt entered the postconsumer waste streams, and 390 kt were recycled and returned to the market in the form of carpet underlayment. The domestic production of polyurethane consumed 1100 kt of crude oil and 1100 kt of natural gas. With the developed polyurethane flow map, we point out the limitation of the existing mechanical recycling methods and identify that glycolysis, a chemical recycling method, can be used to recycle the main components of postconsumer polyurethane waste. We also explore how targeting biobased pathways could influence the supply chain and downstream markets of polyurethane and reduce the consumption of fossil fuels and the exposure to toxic precursors in polyurethane production.
引用
收藏
页码:14215 / 14224
页数:10
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