BF3•OEt2-catalyzed intermolecular reactions of arylmethylenecyclopropanes with (E)-1,1,3-triarylprop-2-en-1-ols

被引：9
|
作者：
Wu, Lei [1 ]
Shi, Min [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
TETRAHEDRON | 2011年 / 67卷 / 32期
基金：
中国国家自然科学基金;
关键词：
Lewis acid; Arylmethylenecyclopropanes; 1,2-Aryl migration; Ring opening; Ring enlargement; Carbon cationic intermediate; CATALYZED CASCADE REACTIONS; RING-OPENING REACTIONS; UNIQUE TETRASUBSTITUTED ALKENE; ACID-MEDIATED CYCLOADDITION; PYRROLIDINE SKELETONS; METHYLENECYCLOPROPANES; LEWIS; ALDEHYDES; ALKYLIDENECYCLOPROPANES; BICYCLOPROPYLIDENE;
D O I：
10.1016/j.tet.2011.06.009
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
BF3 center dot OEt2-catalyzed intermolecular reactions of arylmethylenecyclopropanes with (E)-1,1,3-triarylprop-2en-1-ols produced the corresponding triene compounds, alcoholic derivatives or cyclobutane derivatives in moderate to excellent yields under mild conditions. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5732 / 5739
页数：8
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