Synthesis and characterization of heterometallic dinuclear and trinuclear platinum metal complexes

被引：0
|
作者：
Pandey, DS
Pandeya, KB
Tripathi, IP
Agarwala, UC
机构：
[1] CHITRAKOOT GRAMODAYA VISHWAVIDYALAYA,DEPT CHEM,CHITRAKOOT 485336,INDIA
[2] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1996年 / 26卷 / 05期
关键词：
D O I：
10.1080/00945719608004333
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Heterometallic binuclear complexes of the general formula [(EPh(3))(2)Cp-Ru-cdc-Pt(PPh(3))(2)]BF4 and trinuclear complexes of formula [M(cdc)(2){RuCp(PPh(3))(2)}(2)] {where E = P, As; M = Pt, Pd; Cp = eta(5)-C5H5 and cdc(2-) = (S--)(2)C=N-C=N which may act as a polyfunctional bridging ligand) have been synthesized. These complexes have been characterised on the basis of elemental analyses and spectroscopic data (IR, UV-vis, H-1 and C-13 NMR). Spectroscopic data suggest that the Pt or Pd and Ru(II) are bonded via a cyanide bridge from cdc.
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页码：761 / 773
页数：13
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