Low-cost biochar adsorbents prepared from date and delonix regia seeds for heavy metal sorption

被引:64
|
作者
Pal, Dan Bahadur [1 ]
Singh, Arvind [2 ]
Jha, Jay Mant [3 ]
Srivastava, Neha [2 ]
Hashem, Abeer [4 ]
Alakeel, Maha Abdullah [4 ]
Abd Allah, Elsayed Fathi [5 ]
Gupta, Vijai Kumar [6 ,7 ]
机构
[1] Birla Inst Technol, Dept Chem Engn, Jharkhand 835215, Bihar, India
[2] Indian Inst Technol BHU, Dept Chem Engn & Technol, Varanasi 221005, Uttar Pradesh, India
[3] Maulana Azad Natl Inst Technol, Dept Chem Engn, Bhopal 462003, Madhya Pradesh, India
[4] King Saud Univ, Coll Sci, Bot & Microbiol Dept, POB 2460, Riyadh 11451, Saudi Arabia
[5] King Saud Univ, Coll Food & Agr Sci, Plant Prod Dept, POB 2460, Riyadh 11451, Saudi Arabia
[6] Scotlands Rural Coll SRUC, Biorefining & Adv Mat Res Ctr, Kings Bldg,West Mains Rd, Edinburgh EH9 3JG, Midlothian, Scotland
[7] Scotlands Rural Coll SRUC, Ctr Safe & Improved Food, Kings Bldg,West Mains Rd, Edinburgh EH9 3JG, Midlothian, Scotland
关键词
Arsenic removal; Adsorption; Biochar; Date seeds; Delonix regia seed; PALM BIOMASS; COPPER IONS; ADSORPTION; REMOVAL; KINETICS; PYROLYSIS; WASTEWATERS; MECHANISMS; ISOTHERM;
D O I
10.1016/j.biortech.2021.125606
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, low-cost biochar as bio-adsorbents derived from locally accessible delonix regia seed and date seeds were explored for heavy metal environmental cleaning. These prepared biochars were characterized by proximate and elemental analyses, CHNS/O analysis, Fourier-transformed infrared spectroscopy and thermogravitational methods. Bio-sorbent's ability to adsorb arsenic ions in synthetic wastewater was studied and optimized at varying solution pH, adsorbent dose, and starting metal concentrations. Experimentation and optimization studies were also carried out with the help of Design-software 6.0.8. The trials were designed by using response-surface methods, which includes three components and stages of Box-Behnken design. Date seeds derived-biochars eliminated 95% of arsenic from synthetic wastewater, whereas Delonix regia seeds removed 93.8%. The kinetics, isotherms and mechanism of As adsorption were also postulated. This study proposes that these seed's biochars might be employed as an effective, low-cost, and environmentally friendly adsorbent to remove heavy metals from the environment.
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页数:10
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