Measurement and correlation of excess molar enthalpy at various temperatures -: Acetonitrile plus diethylamine or s-butylamine mixtures

As a continuation of our studies on excess functions of binary systems containing acetonitrile-amines mixtures, in this work excess molar enthalpy (H-m) of acetonitrile+diethylamine or s-butylamine mixtures have been determined as a function of composition at 288.15, 293.15, 298.15 and 303.15 K at atmospheric pressure using a modified 1455 Parr adiabatic calorimeter. The excess enthalpy data are positive for both systems over the whole composition range. ERAS-Model calculations allowing for self-association and cross-association of the components were performed. The results of the calculations and the influence of temperature and isomers chains on the excess enthalpy behavior are discussed.