Temperature evolution of optical transition 7F6 ⇒ 5D4 in Tb3Ga5O12 and Tb2(MoO4)3 from 4.2 to 300 K

被引:1
|
作者
Nizhankovskiy, V., I [1 ]
机构
[1] Polish Acad Sci, Inst Low Temp & Struct Res, Ul Okolna 2, PL-50422 Wroclaw, Poland
关键词
Rare earth alloys and compounds; Optical properties; FEATURES;
D O I
10.1016/j.jallcom.2022.163880
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Absorption spectra of Tb3Ga5O12 and Tb-2(MoO4)(3) are measured in temperature range from 4.2 to 300 K. Two low-energy lines appear above 20 K. This lines are ascribed to the vibronic-assisted optical absorption. Energy of the zero-point vibrations should be taken into account when optical data are used in calculation of the crystal electric field parameters. (C) 2022 Elsevier B.V. All rights reserved.
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页数:5
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