Colleges and universities are the important field of socialism core value education, and college students are important participants in the education of socialism core value. With the arrival of the network age, its technical characteristics had a profound impact of the college students' socialism core value education. And the internet does not only bring the value and technical support, but also brings some challenges to the education of college students' socialism core value. Facing the new situation of ideological education field, we should innovate our ideas of the college students' socialism core value education, integrate the college students' socialism core value educational structural form, and improve the college students' socialism core value education evaluation system. Foster strengths and circumvent weaknesses, in order to make further improvement on the effectiveness of the education of the socialism core Value of college students in the network age.