Nature and physicochemical features of the incrusted white decoration on pottery from two sites in Bulgaria, dated to the chalcolithic period (IV mill BC)
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作者:
Pirovska, Angelina
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St Kliment Ohridski Univ, Sofia 1504, BulgariaSt Kliment Ohridski Univ, Sofia 1504, Bulgaria
Pirovska, Angelina
[1
]
Antonova, Krassimira
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Bulgarian Acad Sci, Inst Solid State Phys, 72 TzarigradskoChaussee, BU-1784 Sofia, BulgariaSt Kliment Ohridski Univ, Sofia 1504, Bulgaria
Antonova, Krassimira
[2
]
Malcheva, Galina
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Bulgarian Acad Sci, Inst Solid State Phys, 72 TzarigradskoChaussee, BU-1784 Sofia, BulgariaSt Kliment Ohridski Univ, Sofia 1504, Bulgaria
Malcheva, Galina
[2
]
Tankova, Vani
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Bulgarian Acad Sci, Inst Solid State Phys, 72 TzarigradskoChaussee, BU-1784 Sofia, BulgariaSt Kliment Ohridski Univ, Sofia 1504, Bulgaria
Tankova, Vani
[2
]
Blagoev, Kiril
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Bulgarian Acad Sci, Inst Solid State Phys, 72 TzarigradskoChaussee, BU-1784 Sofia, BulgariaSt Kliment Ohridski Univ, Sofia 1504, Bulgaria
Blagoev, Kiril
[2
]
机构:
[1] St Kliment Ohridski Univ, Sofia 1504, Bulgaria
[2] Bulgarian Acad Sci, Inst Solid State Phys, 72 TzarigradskoChaussee, BU-1784 Sofia, Bulgaria
We present the investigations on the nature of the white paste used for incrustations on pottery from Early and Late Chalcolithic period (IV mill BC) found in two regions on the territory of Bulgaria. Fourier Transformed Infrared (FTIR) spectroscopy, Laser-Induced Breakdown Spectroscopy (LIBS) and X-ray powder diffraction (XRD) were carried out for determination of the material constituents and structure. The resulting spectra revealed different consistency of the incrusted white substance: bioapatite, gypsum and calcites based on inorganic mixtures, thus proving the knowledge of various techniques in the ancient manufacturing process and the possible ties with the prehistorical Balkans cultures in the near by areas around.