Low-energy d-d excitations in MnO studied by resonant x-ray fluorescence spectroscopy

被引:135
|
作者
Butorin, SM [1 ]
Guo, JH [1 ]
Magnuson, M [1 ]
Kuiper, P [1 ]
Nordgren, J [1 ]
机构
[1] UNIV UPPSALA, DEPT PHYS, S-75121 UPPSALA, SWEDEN
关键词
D O I
10.1103/PhysRevB.54.4405
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We measured the Mn L(alpha,beta) x-ray fluorescence spectra of MnO excited by selected photon energies near the L(2,3) absorption edges. The resulting resonant inelastic x-ray scattering spectra probe low-lying electronic excited states, due to dd and charge-transfer excitations. Using a two-step model and a purely atomic approximation, we reproduce both energies and varying intensities of dd excitations relative to the electronic recombination peak. Our results show that strongly varying line shapes in resonant x-ray emission need not be due to channel interference effects.
引用
收藏
页码:4405 / 4408
页数:4
相关论文
共 50 条
  • [1] d-d excitations in bilayer manganites probed by resonant inelastic x-ray scattering
    Weber, F.
    Rosenkranz, S.
    Castellan, J. -P.
    Osborn, R.
    Mitchell, J. F.
    Zheng, H.
    Casa, D.
    Kim, J. H.
    Gog, T.
    [J]. PHYSICAL REVIEW B, 2010, 82 (08)
  • [2] Origin of Low Energy d-d Excitations Observed on Wet Chemically Prepared Cobalt Bearing Nanoparticles by 2p3d Resonant X-ray Emission Spectroscopy
    van Schooneveld, Matti M.
    Juhin, Amelie
    Campos-Cuerva, Carlos
    Schmitt, Thorsten
    de Groot, Frank M. F.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (27): : 14398 - 14407
  • [3] d-d excitations in manganites probed by resonant inelastic x-ray scattering -: art. no. 047203
    Grenier, S
    Hill, JP
    Kiryukhin, V
    Ku, W
    Kim, YJ
    Thomas, KJ
    Cheong, SW
    Tokura, Y
    Tomioka, Y
    Casa, D
    Gog, T
    [J]. PHYSICAL REVIEW LETTERS, 2005, 94 (04)
  • [4] Revealing the Size-Dependent d-d Excitations of Cobalt Nanoparticles Using Soft X-ray Spectroscopy
    Cui, Zhangzhang
    Xie, Chenlu
    Feng, Xuefei
    Becknell, Nigel
    Yang, Peidong
    Lu, Yalin
    Zhai, Xiaofang
    Liu, Xiaosong
    Yang, Wanli
    Chuang, Yi-De
    Guo, Jinghua
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (02): : 319 - 325
  • [5] Development of a low-energy X-ray fluorescence system combined with X-ray microscopy
    Gianoncelli, A.
    Klatka, T.
    Alberti, R.
    Bacescu, D.
    De Marco, A.
    Marcello, A.
    Longoni, A.
    Kaulich, B.
    Kiskinova, M.
    [J]. 9TH INTERNATIONAL CONFERENCE ON X-RAY MICROSCOPY, 2009, 186
  • [6] Nonresonant inelastic x-ray scattering and energy-resolved Wannier function investigation of d-d excitations in NiO and CoO
    Larson, B. C.
    Ku, Wei
    Tischler, J. Z.
    Lee, Chi-Cheng
    Restrepo, O. D.
    Eguiluz, A. G.
    Zschack, P.
    Finkelstein, K. D.
    [J]. PHYSICAL REVIEW LETTERS, 2007, 99 (02)
  • [7] SOME RECENT DEVELOPMENTS IN LOW-ENERGY X-RAY SPECTROSCOPY
    HENKE, BL
    [J]. BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1980, 25 (08): : 1021 - 1021
  • [8] Resonant X-ray fluorescence spectroscopy of correlated systems: A probe of charge-transfer excitations
    Butorin, SM
    Mancini, DC
    Guo, JH
    Wassdahl, N
    Nordgren, J
    Nakazawa, M
    Tanaka, S
    Uozumi, T
    Kotani, A
    Ma, Y
    Myano, KE
    Karlin, BA
    Shuh, DK
    [J]. PHYSICAL REVIEW LETTERS, 1996, 77 (03) : 574 - 577
  • [9] Inelastic x-ray scattering studies of low-energy charge excitations in graphite
    Hiraoka, N
    Ishii, H
    Jarrige, I
    Cai, YQ
    [J]. PHYSICAL REVIEW B, 2005, 72 (07)
  • [10] Overlap of Cu 3d and F 2p orbitals and low-energy excitations in KCuF3 studied by polarization-dependent x-ray absorption and emission spectroscopy
    Bondino, F.
    Malvestuto, M.
    Magnano, E.
    Zangrando, M.
    Zacchigna, M.
    Ghigna, P.
    Parmigiani, F.
    [J]. PHYSICAL REVIEW B, 2009, 79 (11):