Synthesis of branched polymers by means of living anionic polymerization, 5 - Synthesis of star polymers by reactions of end-functionalized polystyrenes with chloromethylphenyl groups with polymer anions consisting of two polymer chains

被引：0

作者：

Hirao, A ^{[1
]}

Tokuda, Y ^{[1
]}

Morifuji, Y ^{[1
]}

Hayashi, M ^{[1
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Polymer & Organ Mat Dept, Meguro Ku, Tokyo 1528552, Japan

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2001年 / 202卷 / 09期

关键词：

D O I：

10.1002/1521-3935(20010601)202:9<1606::AID-MACP1606>3.0.CO;2-M

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Well-defined five-arm star polymers, having different arms in molecular weight or composition, were synthesized by linking reactions of end-functionalized polystyrenes with two chloromethylphenyl (CMP) groups and polymer anions consisting of two identical or different polymer chains. The polymer anions were prepared by coupling living anionic polymers of styrene or isoprene with 1,1-diphenylethylene (DPE)-end-functionalized polymers. They were then reacted in situ with the CMP-end-functionalized polystyrenes to afford heteroarm star polymers of the AA2′A2″, AA2′B2, and AB2C2 types where the A, B, and C segments were polystyrene, poly(a-methylstyrene), and polyisoprene, respectively. 1H NMR spectroscopy, SEC, vapor pressure osmometry (VPO), and static light scattering measurements evaluated the well-defined architecture of these polymers. © Wiley-VCH Verlag GmbH, 2001.

引用

页码：1606 / 1613

页数：8

共 50 条

[1] Synthesis of end-functionalized polymer by means of living anionic polymerization .7. Reaction of anionic living polymers with perfluoroalkyl halides
Sugiyama, K
Hirao, A
Nakahama, S
[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (10) : 3149 - 3165
[2] Synthesis of end-functionalized polymers by means of living anionic polymerization. 10. Reactions of living anionic polymers with halopropylstyrene derivatives
Hayashi, M
Nakahama, S
Hirao, A
[J]. MACROMOLECULES, 1999, 32 (05) : 1325 - 1331
[3] Synthesis of end-functionalized polymer by means of living anionic polymerization .5. Syntheses of polystyrenes and polyisoprenes with hydroxy and mercapto end groups by reactions of the living polymers with haloalkanes containing silyl ether and silyl thioether functions
Tohyama, M
Hirao, A
Nakahama, S
Takenaka, K
[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (10) : 3135 - 3148
[4] Synthesis of end-functionalized polymers by means of living anionic polymerization .8. Reactions of living anionic polymers with alpha,omega-dihaloalkanes
Hirao, A
Tohoyama, M
Nakahama, S
[J]. MACROMOLECULES, 1997, 30 (12) : 3484 - 3489
[5] Synthesis of well-defined star-branched polymers by coupling reactions of polymer anions consisting of two polymer chains with chain-end-multifunctionalized polystyrenes with benzyl bromide moieties
Hirao, A
Tokuda, Y
[J]. MACROMOLECULES, 2003, 36 (16) : 6081 - 6086
[6] Synthesis of heteroarm star-branched polymers by means of anionic living polymerization
Hirao, A
Matsuo, A
Morifuji, K
Tokuda, Y
Hayashi, M
[J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2001, 12 (11-12) : 680 - 686
[7] Synthesis of end-functionalized polymers by means of living anionic polymerization. 9. Synthesis of well-defined end-functionalized polymers with one, two, three, or four monosaccharide residues
Hayashi, M
Loykulnant, S
Hirao, A
Nakahama, S
[J]. MACROMOLECULES, 1998, 31 (07) : 2057 - 2063
[8] Synthesis of well-defined polymers end-functionalized with crosslinkable aziridine groups by living anionic polymerization
Kobayashi, M
Uchino, K
Ishizone, T
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (18) : 4126 - 4135
[9] SYNTHESIS OF END-FUNCTIONALIZED POLYMER BY MEANS OF LIVING ANIONIC-POLYMERIZATION .4. SYNTHESIS OF POLYISOPRENE AND POLYSTYRENE WITH EPOXY TERMINI BY REACTION OF THEIR ANIONIC LIVING POLYMERS WITH 2-BROMOETHYLOXIRANE
TAKENAKA, K
HIRAO, A
NAKAHAMA, S
[J]. POLYMER INTERNATIONAL, 1995, 37 (04) : 291 - 295
[10] Synthesis of branched polymers by means of living anionic polymerization. 12. Anionic synthesis of well-defined star-branched polymers by using chain-end-functionalized polystyrenes with dendritic benzyl bromide moieties
Hirao, A
Haraguchi, N
[J]. MACROMOLECULES, 2002, 35 (19) : 7224 - 7231

← 1 2 3 4 5 →