Selective Photocatalytic Conversion of Benzyl Alcohol to Benzaldehyde by Antimony(V) Porphyrin Metal-Organic Frameworks under Visible-Light Irradiation

被引：6
|
作者：
Xie, Dale [1 ]
Li, Shihao [1 ]
Yang, Wenqing [1 ]
Fan, Shilu [1 ,2 ]
Feng, Yi-Si [1 ,2 ]
机构：
[1] Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Peoples R China
[2] Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Hefei 230009, Peoples R China
来源：
CHEMISTRYSELECT | 2022年 / 7卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Antimony porphyrin; PCN-224; Photocatalysis; Oxidation; Axial ligand; PHOTOCHEMICAL OXYGENATION; SINGLET OXYGEN; OXIDATION; EFFICIENT; CYCLOHEXENE; WATER; ALDEHYDES; LINKER; MOF;
D O I：
10.1002/slct.202103521
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Porphyrin-based MOFs have great structural tunability and prominent catalyst activity. In this work, a series of antimony porphyrin MOFs (PCN-224(Sb)-L) were synthesized to efficiently selective oxidate benzyl alcohol under visible light. To investigate the effects of the Sb-axial ligands on photocatalytic activity, the oxidation of benzyl alcohol to corresponding benzaldehyde was utilized as a model reaction. Within these three analogues of PCN-224(Sb)-L, PCN-224(Sb)-OH exhibit a remarkable 96 % conversation and 100 % selectivity of the benzaldehyde with an extremely high turnover number (TON) of 9300.
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页数：6
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