A growing family: New structures of coordination polymers containing adamantane-shaped phosphorus-nitrogen cage ligands

被引：4

作者：

Spore, Alex B. ^{[1
]}

Rizzo, Natalie M. ^{[1
]}

Noll, Bruce C. ^{[2
]}

Sommer, Roger D. ^{[1
]}

机构：

[1] Depaul Univ, Dept Chem, Chicago, IL 60614 USA

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

INORGANICA CHIMICA ACTA | 2010年 / 364卷 / 01期

基金：

美国国家科学基金会;

关键词：

Coordination polymers; Phosphorus-nitrogen; Copper;

D O I：

10.1016/j.ica.2010.08.052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new structurally characterized coordination polymers containing the P-4(NR)(6) ligand system are described. A convenient one-pot synthesis of P-4(NR)(6) (R = benzyl) via reaction of lithiated primary amine with phosphorus trichloride demonstrates an expanded scope for the preparation of this adamantane-type structure. Reactions of P-4(NR)(6) (R = Et, Bn) with cuprous iodide yield different products due to the differences in steric demands of the ligands. (C) 2010 Elsevier B. V. All rights reserved.

引用

页码：261 / 265

页数：5

共 24 条

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